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近年来日用品不断地推陈出新,对表面装饰提出了更高的要求,多色电镀的精饰件很受消费者欢迎,应用非常广泛,从标牌、工艺品到五金、锁具、灯具、眼镜、钟表等都有应用。塑料属于难镀材料,虽然有成熟工艺,报道也较多,但对于双色电镀及多色电镀工艺报道还没见到过。目前,某种塑料商标标牌的电镀(仿金+铬)加工价格高达8~9元/dm2,市场广,效益好。本文对生产较成熟的双色电镀工艺做一简介。 2工艺流程及注意事项 除应力→化学除油→化学粗化→盐酸洗→胶体钯直接活化→解胶→化学镀镍→毛刷刷洗→闪镀(焦磷酸盐镀铜)→酸性光亮镀铜→光亮镀镍→稀酸活化→镀仿金→钝化→烘干→局部点清漆→烘干→退除局部仿金层→稀H2SO4活化→镀铬→烘干→检验。以上工艺流程省略了水洗工序。但水洗一定要有,且要清洗彻底。活化与解胶后的水洗严禁用水猛冲。每道工序操作时要防止零件之间擦伤碰毛。零件装网、装筐或从网、筐中倒出时要轻轻操作,最好倒在盛水的盆里,用水的浮力来防止零件之间擦伤。 2.1除应力将塑料件放在烘箱中,70℃下保温2h。 2.2化学除油 氢氧化钠40g/L,磷酸钠30g/L,碳酸钠20g/L,OP乳化剂1~3g/L,θ60~70℃,t10~15min 除油过程中,应轻轻搅动塑料件,以加快除油速度。也可将粗化后的回收液加温到不超过70℃下除油。 2.3化学粗化[1]CrO3400g/L,H2SO4(d=1.84)200mL/L,H2O600mL/L相对密度1.45θ70℃,t10~15min只要严格按照此配方和工作条件操作,不会发生粗化不足或粗化过度。 2.4盐酸洗HCl(d=1.19)100~200mL/L,t1~3min盐酸洗涤能除去塑料表面残留的粗化液和吸附的Cr3+。经过盐酸洗涤后,能用肉眼观察到塑料表面由淡淡的暗绿色变得白一些。 2.5胶体钯直接活化法PdCl2·2H2O0.5~1g/L,SnCl2·2H2O50~100g/L,HCl(d=1.19)200~300mL/L,θ50~60℃,t5~10min氯化钯浓度不要太高,否则配槽成本高,带出损失大。一些资料[2]报道的配方中,氯化钯质量浓度低于0.5g/L,笔者在生产中证实是不可行的,即使延长活化时间到30min以上,温度提高到60℃以上,依然会出现露塑,生产效率低,成品率低。为防止清洗水的带入使活化液稀释而产生沉淀,塑料件进入胶体钯直接活化液以前,先在胶体钯溶液后的回收液中预浸5min,不清洗直接进行胶体钯活化。禁止将化学镀镍不合格的塑料件不退镍层直接进入胶体钯溶液补充活化,以免使胶体钯活化液引入Ni2+,降低活化液的活性和稳定性。 2.6解胶NaOH100~300g/Lt3~5min碱液解胶法比酸液解胶速度快,彻底且无需加热,而酸液解胶需较浓的酸且要加热。 2.7化学镀镍、焦磷酸盐镀铜、酸性光亮镀铜、光亮镀镍、镀仿金及镀铬溶液成分、配制、使用维护与常规镀液相同,可参考有关资料。 2.8毛刷刷洗化学镀镍层表面可能存在固体颗粒或其它污物,电镀后容易产生粗糙和花脸,这在大面积镀件上很明显,所以增加了一道毛刷刷洗工序。刷洗时不要用太硬的毛刷,以免划伤化学镀镍层。 2.9点清漆镀仿金后,经钝化再点透明清漆可提高金层的抗变色能力,也起到绝缘作用,阻止仿金层上再镀上铬。塑料件不耐温,要求透明清漆是常温自干型或低温烘干型。局部点透明清漆时要仔细,防止在需镀铬的花纹部位上点漆。如需烘干漆膜,温度不要超过70℃。 3结束语 多色电镀市场前景看好,效益佳,但起步晚无报道可参考。本文介绍的双色电镀品,金黄色(仿金)背景衬托出白亮(铬)花纹图案,外观很漂亮。但是,亮镍层经过镀仿金、钝化、烘干、点清漆、烘干、局部退除仿金层等众多工序,需24h以上,会发生严重的钝化。尽管采取了稀H2SO4较长时间浸泡活化,但镀铬正品率还是太低(能达到40%左右),制约着经济效益。相信随着电镀工作者的努力,其它如缎面镍+仿金、黑镍+仿金、红古铜+黑镍、白镍+黑镍+金色、红古铜+黑镍+仿金……多色电镀工艺都必将会更加成熟。
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