From 9:00 to 12:00,he has English class.
若表一般状况(他每天都是这样上课),就用has/take;若表示过去某件事(曾经某天他是这样上课),就把has/take改成had/took
During 9:00 to 12:00, he was in class.
He is studying between 9 o'clock and 12 o'clock.
He has classes from 9:00 to 12:00.
He spoke English from 09:00 to 12:00 in class.