CH3COOH+NaOH=CH3COONa+H2O
CH3COONa呈碱性,溶液刚好呈中性,所以醋酸要过量
剩余醋酸浓度c(CH3COOH)=(c-0.02)/2
电荷守恒:c(CH3COO-)+c(OH-)=c(Na+)+c(H+)
溶液呈中性,c(OH-)=c(H+)
所以c(CH3COO-)=c(Na+) =0.02/2=0.01(mol/L)
CH3COOH== CH3COO- + H+
平衡时 (c-0.02)/2 0.01 10^-7
K=c(CH3COO-)*c(H+)/c(CH3COOH)
=0.01*10^-7 / [(c-0.02)/2 ]
=2*10^-9/(c-0.02)
Ka(HAc)=0.02*10^-7/(c-0.02)
(c-0.0004)/(c-0.02)